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12. Eve Harrington (Anne Baxter) in 'All About Eve'
Beware backstage admirers! In this classic film, actress Margo Channing (Bette Davis) discovers that her biggest fan, Eve Harrington (Anne Baxter), is actually her biggest rival. Eve lays on the charm with all of Margo's friends and colleagues and, sure enough, she's soon replacing her onstage.